Vampire Lady

 Originally, the photo of the lady drinking from the wine glass looked like this:

 After learning how to use:
1) Quick Selection Tool (W) This is how I selected the woman's face.
2) Desaturation (I changed the color of the woman's face by selecting Image/ Adjustments/ Desaturate)
3) Hue/Saturation tool was the second step after Desaturation
4) Layer Masking (I had a total of 2 layers and 1 Layer mask on the copy)
5) Zoom (Z)
6) Brush (B)
I was able to make the photo look like this: